JAMES AUSTIN COMPANY -- AUSTIN A-1 BLEACH SODIUM HYPOCHLORITE SOLUTION. -- 6810-00-598-7316
===================== Product Identification ===================== Product ID:AUSTIN A-1 BLEACH SODIUM HYPOCHLORITE SOLUTION. MSDS Date:02/24/1998 FSC:6810 NIIN:00-598-7316 Status Code:A === Responsible Party === Company Name:JAMES AUSTIN COMPANY Address:DOWNIEVILLE ROAD Box:827 City:MARS State:PA ZIP:16046 Country:US Info Phone Num:412-625-1535 Emergency Phone Num:(800)424-9300 Chemtrec Ind/Phone:(800)424-9300 CAGE:62316 === Contractor Identification === Company Name:JAMES AUSTIN COMPANY Address:DOWNIEVILLE ROAD Box:827 City:MARS State:PA Country:US Phone:412-625-1535 CAGE:62316 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM HYPOCHLORITE CAS:7681-52-9 RTECS #:NH3486300 Minumum % Wt:5.25 Maxumum % Wt:5.5 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:SODIUM HYDROXIDE CAS:1310-73-2 RTECS #:WB4900000 Minumum % Wt:.1 Maxumum % Wt:.22 OSHA PEL:2 MG/M3 CEILING ACGIH TLV:2 MG/M3 CEILING EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== Health Hazards Acute and Chronic:IRRITANT; MAY CAUSE SEVERE SKIN AND EYE IRRITATION OR CHEMICAL BURNS TO BROKEN SKIN. VAPORS EXTREMELY IRRITATING TO EYES AND RESPIRATORY TRACT. HARMFUL AND POTENTIALLY FATAL IF SWALLOWED. IF MIXED WIT H OTHE PROHIBITED CHEMICALS OR MATERIALS, CHLORINE GAS WILL BE RELEASED WHICH IS ALSO IRRITATING TO EYES, LUNGS MUCOUS MEMBRANES AND IN SOME CASES BE FATAL. Explanation of Carcinogenicity:THIS PRODUCT DOES NOT CONTAIN ANY KNOWN OR ANTICIPATED CARCINOGENS ACCORDING TO THE CRITERIA OF THE NTP ANNUAL REPORT ON CARCINOGENS AND OSHA 29 CFR 1910, Z. Effects of Overexposure:INGESTION: CAN CAUSE CORROSION OF MUCOUS MEMBRANES, SEVERE ESOPHAGEAL BURNS AND PERFORATION OF ESOPHAGUS OR STOMACH. INHALATION: INHALATION OF VAPORS CAN CAUSE BRONCHIAL IRRITATION, COUGHING, DIFF ICULTY IN BREATHING, NAUSEA AND PULMONARY EDEMA. EYE CONTACT: IRRITATING TO THE EYES, MAY CAUSE SEVERE AND PERMANENT DAMAGE. SKIN CONTACT: SEVERE IRRITATING; CONTACT CAN PRODUCE BLISTERING AND ECZEMA. ======================= First Aid Measures ======================= First Aid:INGESTION:DO NOT INDUCE VOMITING.IMMEDIATELY DRINK LARGE QUANTITY OF WATER/MILK.DO NOT GIVE LIQUIDS IF VICTIM IS UNCONSCIOUS.DO NOT USE ACIDIC ANTIDOTES/SODIUM BICARBONATE(BAKING SODA).DO NOT ADMINIST ER ALCOHOL.CALL PHYSICIAN/POISON CONTROLCENTER IMMEDIATELY.INHALATION:IF EXPOSED TO EXCESSIVE VAPOR LEVELS,REMOVE TO FRESH AIR&SEEK MEDICAL ATTENTION IF COUGH/OTHER SYMPTOMS DEVELOP.EYE:IMMEDIATELY FL USH EYE W/PLENTY OF COOL,RUNNING WATER.REMOVE CONTACT LENSES IF COUGH OR OTHER SYMPTOMS DEVELOP.SKIN:FLUSH AFFECTED AREA W/COPIOUS AMOUNTS OF WATER&WASH W/SOAP&WATER. ===================== Fire Fighting Measures ===================== Extinguishing Media:IF INVOLVED IN A FIRE, ALCOHOL FOAM, CARBON DIOXIDE, DRY CHEMICAL OR WATER FOG. USE EXTINGUISHING MEDIA THAT IS APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:AVOID FUMES FROM SPILLED OR EXPOSED LIQUID. FIREFIGHTERS SHOULD WEAR FULL PROTECTIVE CLOTHING AND OSHA/NIOSH SELF-CONTAINED BREATHING APPARATUS. COOL FIRE-EXPOSED CONTAINERS WITH WATER SPRAY FROM A SAFE DISTANCE. Unusual Fire/Explosion Hazard:SODIUM HYPOCHLORITE BLEACH IS A STRONG OXIDIZING AGENT AND DECOMPOSES WHEN HEATED. DECOMPOSITION PRODUCTS MAY CAUSE CONTAINERS TO EXPLODE. VIGOROUS REACTIONS MAY OCCUR WITH ORGANIC MATERIALS OR OXID IZABLE MATERIALS, CAUSING FIRES. ================== Accidental Release Measures ================== Spill Release Procedures:DILUTE PRODUCT BY FLOODING AREA WITH LARGE QUANITY OF WATER AND FLUSH TO SANITARY SEWER. LARGE SPILLS: CONTAIN RUN-OFF DIKING WITH SUITABLE MATERIAL. SOAK UP LIQUID ON INERT ABSORBENT AND TRANSFER TO APPROVED CONTAINER. PREVENT SPILL FROM ENTERING SEWER OR WATERWAYS. ====================== Handling and Storage ====================== Other Precautions: ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT NORMALLY NECESSARY; USE NIOSH APPROVED RESPIRATOR FOR CONCENTRATED VAPORS. Ventilation:USE LOCAL VENTILATION TO REMOVE VAPORS AT THE SOURCE. Protective Gloves:REQUIRED; USE IMPERVIOUS PVC OR NEOPRENE WITH LONG GAUNTLET. Eye Protection:GOGGLES OR FACE SHIELD Other Protective Equipment:FACILITIES USING THIS PRODUCT MUST BE EQUIPPED WITH AN EYEWASH STATION. Work Hygienic Practices:AVOID BREATHING VAPORS. DO NOT STORE NEAR FOOD STUFFS, WATER OR FEED. PROTECT EYES, SKIN AND CLOTHING FROM CONTACT WITH THIS PRODUCT. * Supplemental Safety and Health GOGGLES SHOULD BE CHEMICAL SPLASH TYPE. FACE SHIELD IS BEST CHOICE. APRON: RECOMMENDED TO AVOID SKIN CONTACT AND PROTECT CLOTHING FROM DAMAGE. ================== Physical/Chemical Properties ================== Boiling Pt:=100.C, 212.F B.P. Text:212F Melt/Freeze Pt:=-2.2C, 28.F M.P/F.P Text:28F Vapor Pres:1705 MM HG@20 C Spec Gravity:1.080 pH:12.0-12.8 Solubility in Water:COMPLETE Appearance and Odor:CLEAR PALE YELLOW LIQUID. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NEVER MIX SOLUTIONS CONTAINING AMMONIA. INCOMPATIBILTY: ACIDS, AMMONIA, ETHER, UREA, OXIDIZABLE MATERIALS, SOAPS, OILS, GREASES, PHENOLIC DISIINFECTANTS AND METALS(INCLUDING NICKEL, COPPER, TIN, ALUMINUM AND IRON). Stability Condition to Avoid:HEAT OR DIRECT SUNLIGHT; TEMPERATURES ABOVE 85F. Hazardous Decomposition Products:CHLORINE GAS-FROM CONTACT WITH HIGHLY ACIDIC MATERIALS. CHLORAMINES-FROM CONTACT WITH AMMONIA. POLYCHLORINATED PHENOLS-FROM CONTACT WITH PHENOLIC DISINFECTANTS. =================== Toxicological Information =================== Toxicological Information:IF IRRITATION DEVELOPS OR PERSISTS, GET MEDICAL ATTENTION. REMOVE CLOTHING AND WASH BEFORE REUSE. NOTE: INFORMATION PERTAINING TO INGESTION TOXICOLOGY, THERAPY, SYMPOMATOLOGY AND TREATMENT CAN BE FOUND IN CLINICAL TOXICOLOGY OF COMMERCIAL PRODUCTS, AUTHORED BY GOSSELIN, SMITH AND HODGE AND PUBLISHED BY WILLIAMS & WILKINS, BALTIMORE MARYLAND. ===================== Ecological Information ===================== Ecological:CONSIDERED TO BE BIODEGRADIBLE.*BOOTS: RECOMMENDED TO PROTECT SHOES AND FEET WHEN USING PRODUCT FOR FLOOR CLEANING. ==================== Disposal Considerations ==================== Waste Disposal Methods: =================== MSDS Transport Information =================== Transport Information:DOT PROPER SHIPPING NAME: HYPOCHLORITE SOLUTION. HAZARD CLASS: 8. UN-NUMBER: 1791. PACKAGE GROUP: III. LABEL/PLACARD: CORROSIVE. RQ: SODIUM HYPOCHLORITE 100LBS. (45.4 KG). ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.